Using a PSA for one character slot?

[Convour]

I am using the brawl- set for everything, but found that there are some cool movesets for specific characters I want to use (i.e. Skyward Sword link moveset).

Can I put the Skyward Sword Link moveset on just the default costume and have all of the other costumes the brawl- moveset?

[Gamma Ridley]

no